发明名称 |
PROCESS FOR PRODUCING DIFLUOROMETHANE |
摘要 |
Difluoromethane is prepared by reacting dichloromethane and hydrogen fluoride in a liquid phase in the presence of a fluorination catalyst under reaction conditions in which the reaction pressure is between 1 and 10 kg/cm<2>ab., and the reaction temperature is between 50 and 150 DEG C, provided that the selected reaction temperature is higher than a temperature at which hydrogen fluoride is not liquefied under the selected reaction pressure. Under the above conditions, the conversions of dichloromethane and HF are very high, and amounts of by-products other than R30 are very low, typically less than 0.1 % per difluoromethane, when the unreacted materials are recycled. A material of a reactor is hardly corroded by the reaction using an antimony chlorofluoride and HF which are highly corrosive, as long as the above conditions are maintained. |
申请公布号 |
EP0767158(B1) |
申请公布日期 |
2000.02.09 |
申请号 |
EP19950921110 |
申请日期 |
1995.06.07 |
申请人 |
DAIKIN INDUSTRIES, LIMITED |
发明人 |
TSUDA, TAKEHIDE;YAMADA, YASUFU;SHIBANUMA, TAKASHI |
分类号 |
B01J23/26;C07B61/00;C07C17/20;C07C17/21;C07C17/383;C07C19/08 |
主分类号 |
B01J23/26 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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