| 摘要 |
<p>The invention is a polymerization process for ethylene copolymers having a density less than 0.915 comprising contacting ethylene, one or more α-olefin monomer, and optionally one or more diene monomer, with a catalyst composition comprising the reaction product of at least one organometallic Group 4 metallocene compound derived from a bridged, fused-ring ligand containing biscyclopentadienyl hafnocene, said bridge being a substituted or unsubstituted carbon or silicon atom connecting the biscyclopentadienyl ligands, and a salt of a Group 13 element anionic complex having halogenated aromatic ligands in an essentially tetrahedral structure wherein the aromatic groups are polycyclic fused or pendant aromatic rings. The process is particularly suitable for the preparation of high comonomer content and high molecular weight ethylene-α-olefin plastomers and ethylene-propylene or ethylene-propylene-diene monomer elastomers.</p> |
