发明名称 A CATALYST FOR ASYMMETRIC INDUCTION
摘要 A CATALYST FOR ASYMMETRIC INDUCTION A catalyst for asymmetric induction is provided which comprises an amino acid amide derivative represented by the formula ¢I!: <IMG> (I) wherein R' represents an isopropyl group, etc., R2 and R3 are the same or different and each represents a lower alkyl group, etc., R4 represents a chlorine atom, etc., R5, R6 and R7 are the same or different and each represents a hydrogen atom, etc., and * denotes an abosolute configuration of S or R, and a titanium (IV) alkoxide. Optically active cyanohydrins are obtained in high yield and at high purity by addition of hydrogen cyanide to aldehyde compounds in the presence of the above mentioned catalyst.
申请公布号 CA2087472(A1) 申请公布日期 1993.09.19
申请号 CA19932087472 申请日期 1993.01.18
申请人 SUMITOMO CHEMICAL COMPANY, LIMITED 发明人 MORI, ATSUNORI;INOUE, SHOHEI
分类号 B01J31/02;C07B53/00;C07B61/00;C07C251/24;C07C253/08;C07C253/30;C07C253/34;C07C255/16;C07D295/185;(IPC1-7):C07C251/24;B01J21/06;C07C255/17;B01J27/24;C07C255/36;C07D307/54;C07D317/64 主分类号 B01J31/02
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