A process is disclosed for the particle form polymerization of olefins. The process employs a titanium-containing having hydrocarbon soluble titanium components. The resulting catalyst is pretreated with an organometallic reducing agent prior to the introduction of the catalyst into the polymerization zone to give a catalyst which can be used satisfactorily in a loop reactor with lower levels of cocatalyst.
申请公布号
US5275992(A)
申请公布日期
1994.01.04
申请号
US19920986230
申请日期
1992.12.07
申请人
PHILLIPS PETROLEUM COMPANY
发明人
MITCHELL, KENT E.;MCDANIEL, MAX P.;WELCH, M. BRUCE;BENHAM, ELIZABETH A.;CONE, GROVER W.