ROOM TEMPERATURE VULCANISABLE ACETOXYSILOXANE BLOCK COPOLYMER

摘要

1,273,908. Siloxane block copolymer. DOW CORNING CORP. 13 Oct., 1970 [1 Dec., 1969], No. 48564/70. Heading C3T. A room temperature vuloanizable (RTV) composition stable in the absence of moisture and curable upon exposure to moisture comprises an organisoloxane block copolymer which comprises: (A) 16-84 mol per cent of diorganosiloxane units wherein the units are bonded through Si-O-Si bonds forming a block having 6-350 units/block, the polydiorganosiloxane being at least 80 mol per cent dimethylsiloxane units and any remaining units being phenylmethyl- or monomethyl-siloxane units; (B) 11 to 77 mol per cent organosiloxane units R x SiO( 4-x)/2 where x = 1-1À3, R is aryl, C 1 _ 3 alkyl, or vinyl, at least 50% R being aryl, the units comprising a block of at least 3 units which are mono- or diorganosiloxane units; and (C) from 2-27 mol per cent terminating acetoxysiloxane units R1Si(OCOCH 3 ) y O 3(-y)/2 where y = 1À8-2, R1 is a C 1 _ 5 alkyl, phenyl or vinyl radical. The hydroxylated block copolymer can be prepared by coupling and cohydrolysing the hydroxyl terminated polydiorganosiloxane (A) with a trifunctional organosilane in the proper proportions. Thus in a specific example a mixture of C 6 H 5 SiCl 3 , C 6 H 5 CH 3 SiCl 2 in toluene is added to a mixture of hydroxyl-terminated polydimethylsiloxane, toluene, HCl and H 2 O with stirring and then azeotroped to remove residual HCl and H 2 O. In an alternative method the hydroxylated block copolymer is made by coupling the hydroxyl terminated polydiorganosiloxane (A) with an aromatic containing organosiloxane resin (B) having hydroxyl groups, by reaction with a trifunctional silane under anhydrous conditions. The coupling can take place in the presence of amine catalysts such as pyridine, alphapicoline and n-butylamine. The resulting block copolymer produced by either method is then reacted with the monoorganotriacetoxysilane (C) to yield the RTV composition. Reactive diluents such as acetoxy silicon compounds particularly R1Si(OCOCH 2 ) 3 , or non-reactive diluents such as organic solvents can be added to the composition to control the extrusion rate. The compositions can be used as release coatings and adhesives. Substrates which can be bonded by the compositions include glass, ceramics, metals such as Al, steel and Cu, wood, paper, thermoplastics, cellulose aectate-butyrate and leather.