Methods of making single-layer lithium ion battery separators having nanofiber and microfiber constituents

摘要

An insulating (nonconductive) microporous polymeric battery separator comprised of a single layer of enmeshed microfibers and nanofibers is provided. Such a separator accords the ability to attune the porosity and pore size to any desired level through a single nonwoven fabric. Through a proper selection of materials as well as production processes, the resultant battery separator exhibits isotropic strengths, low shrinkage, high wettability levels, and pore sizes related directly to layer thickness. The overall production method is highly efficient and yields a combination of polymeric nanofibers within a polymeric microfiber matrix and/or onto such a substrate through high shear processing that is cost effective as well. The separator, a battery including such a separator, the method of manufacturing such a separator, and the method of utilizing such a separator within a battery device, are all encompassed within this invention.

主权项

1. A method of forming a battery separator of a single layer of fabric, wherein said single-layer battery separator exhibits a maximum thickness of 250 microns, wherein said battery separator includes a combination of microfiber and nanofiber constituents, and wherein said microfibers exhibiting a minimum width of 3000 nm and nanofibers exhibiting a maximum width of 1000 nm, said method comprising the steps of:
a) providing an aqueous solvent; b) introducing therein a plurality of nanofibers to form a nanofiber dispersion within an aqueous solvent; c) mixing said nanofiber dispersion in a hydropulper; d) introducing a plurality of microfibers to form a microfiber/nanofiber dispersion within an aqueous solvent; e) introducing said highly sheared dispersion within a paper making machine, wherein said machine includes vacuum slots to remove water; f) producing a web of microfiber/nanofiber material through said machine of step “e,” wherein machine includes the application of slot vacuum pressure of at most 0.25 bar of vacuum; and g) drying said web.