发明名称 Substituted N-(tetrazol-5-yl)- and N-(triazol-5-yl)pyridin-3-yl-carboxamide compounds and their use as herbicides
摘要 N-(tetrazol-5-yl)- and N-(triazol-5-yl)pyridin-3-yl-carboxamides of formula I and their use as herbicides,; The invention relates to N-(tetrazol-5-yl)- and N-(triazol-5-yl)pyridin-3-yl-carboxamides of formula I and their use as herbicides. In said formula I, B represents N or CH, whereas R, R1, R3, R4 and R5 represent groups such as hydrogen, halogen or organic groups such as alkyl or phenyl.
申请公布号 US9398768(B2) 申请公布日期 2016.07.26
申请号 US201314396873 申请日期 2013.04.15
申请人 BASF SE 发明人 Kraus Helmut;Witschel Matthias;Seitz Thomas;Newton Trevor William;Parra Rapado Liliana;Kreuz Klaus;Hutzler Johannes;Pasternak Maciej;Lerchl Jens;Evans Richard Roger
分类号 C07D401/12;A01N43/713;A01N43/653 主分类号 C07D401/12
代理机构 Brinks Gilson & Lione 代理人 Brinks Gilson & Lione
主权项 1. A compound of formula I, wherein B is N; R is selected from the group consisting of hydrogen, C1-C6-alkyl, C3-C7-cycloalkyl, C3-C7-cycloalkyl-C1-C4-alkyl, where the C3-C7-cycloalkyl groups in the two aforementioned radicals are unsubstituted or partially or completely halogenated, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-haloalkoxy-C1-C4-alkyl, Rb—S(O)n—C1-C3-alkyl, Rc—C(═O)—C1-C3-alkyl, RdO—C(═O)—C1-C3-alkyl, ReRfN—C(═O)—C1-C3-alkyl, RgRhN—C1-C3-alkyl, phenyl-Z where phenyl is unsubstituted or substituted by 1, 2, 3 or 4 groups R′, which are identical or different; R1 is selected from the group consisting of cyano-Z1, halogen, nitro, C1-C8-alkyl, C2-C8-alkenyl, C2-C8-alkynyl, C1-C8-haloalkyl, C1-C8-alkoxy, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkoxy-C1-C4-alkoxy-Z1, C1-C4-alkylthio-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkylthio-Z1, C2-C6-alkenyloxy, C2-C6-alkynyloxy, C1-C6-haloalkoxy, C1-C4-haloalkoxy-C1-C4-alkyl, C1-C4-haloalkoxy-C1-C4-alkoxy-Z1, R1b—S(O)k—Z1, phenoxy-Z1, where the cyclic group in phenoxy is unsubstituted or substituted by 1, 2, 3 or 4 groups R11, which are identical or different; R3 is selected from the group consisting of hydrogen, halogen, OH—Z2, NO2—Z2, cyano-Z2, C1-C6-alkyl, C2-C8-alkenyl, C2-C8-alkynyl, C3-C10-cycloalkyl-Z2, C3-C10-cycloalkoxy-Z2, where the C3-C10-cycloalkyl groups in the two aforementioned radicals are unsubstituted or partially or completely halogenated, C1-C8-haloalkyl, C1-C8-alkoxy-Z2, C1-C8-haloalkoxy-Z2, C1-C4-alkoxy-C1-C4-alkoxy-Z2, C1-C4-alkylthio-C1-C4-alkylthio-Z2, C2-C8-alkenyloxy-Z2, C2-C8-alkynyloxy-Z2, C2-C8-haloalkenyloxy-Z2, C2-C8-haloalkynyloxy-Z2, C1-C4-haloalkoxy-C1-C4-alkoxy-Z2, (tri-C1-C4-alkyl)silyl-Z2, R2b—S(O)k—Z2, R2c—C(═O)—Z2, R2dO—C(═O)—Z2, R2eR2fN—C(═O)—Z2, R2gR2hN—Z2, phenyl-Z2a where the cyclic group in phenyl-Z2a is unsubstituted or substituted by 1, 2, 3 or 4 groups R21, which are identical or different; R4 is selected from the group consisting of hydrogen, halogen, cyano, nitro, C1-C4-alkyl and C1-C4-haloalkyl; R5 is selected from the group consisting of halogen, C1-C4-alkyl and C1-C4-haloalkyl; n is 0, 1 or 2; k is 0, 1 or 2; R′, R11, R21 independently of each other are selected from the group consisting of halogen, NO2, CN, C1-C6-alkyl, C3-C7-cycloalkyl, C3-C7-halocycloalkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C1-C6-alkoxy, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkyl, C1-C4-haloalkoxy-C1-C4-alkyl, C1-C4-alkoxy-C1-C4-alkoxy, C3-C7-cycloalkoxy and C1-C6-haloalkyloxy, or two vicinal radicals R′, R11 or R21 together may form a group ═O; Z, Z1, Z2 independently of each other are selected from the group consisting of a covalent bond and C1-C4-alkanediyl; Z2a is selected from the group consisting of a covalent bond, C1-C4-alkanediyl, O—C1-C4-alkanediyl, C1-C4-alkanediyl-O and C1-C4-alkanediyl-O—C1-C4-alkanediyl; Rb, R1b, R2b independently of each other are selected from the group consisting of C1-C6-alkyl, C3-C7-cycloalkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, and phenyl, where phenyl is unsubstituted or substituted by 1, 2, 3 or 4 groups, which are identical or different and selected from the group consisting of halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy and C1-C4-haloalkoxy; Rc, R2c independently of each other are selected from the group consisting of hydrogen, C1-C6-alkyl, C3-C7-cycloalkyl, C3-C7-cycloalkyl-C1-C4-alkyl, where the C3-C7-cycloalkyl groups in the two aforementioned radicals are unsubstituted or partially or completely halogenated, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C1-C4-alkoxy-C1-C4-alkyl, phenyl, and benzyl, where phenyl and benzyl are unsubstituted or substituted by 1, 2, 3 or 4 groups, which are identical or different and selected from the group consisting of halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy and C1-C4-haloalkoxy; Rd, R2d independently of each other are selected from the group consisting of C1-C6-alkyl, C3-C7-cycloalkyl, C3-C7-cycloalkyl-C1-C4-alkyl, where the C3-C7-cycloalkyl groups in the two aforementioned radicals are unsubstituted or partially or completely halogenated, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C1-C4-alkoxy-C1-C4-alkyl, phenyl and benzyl, where phenyl and benzyl are unsubstituted or substituted by 1, 2, 3 or 4 groups, which are identical or different and selected from the group consisting of halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy and C1-C4-haloalkoxy; Re, Rf independently of each other are selected from the group consisting of hydrogen, C1-C6-alkyl, C3-C7-cycloalkyl, C3-C7-cycloalkyl-C1-C4-alkyl, where the C3-C7-cycloalkyl groups in the two aforementioned radicals are unsubstituted or partially or completely halogenated, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C1-C4-alkoxy-C1-C4-alkyl, phenyl and benzyl, where phenyl and benzyl are unsubstituted or substituted by 1, 2, 3 or 4 groups, which are identical or different and selected from the group consisting of halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy and C1-C4-haloalkoxy; R2e, R2f independently of each other have the meanings given for Re, Rf; Rg is from the group consisting of hydrogen, C1-C6-alkyl, C3-C7-cycloalkyl, C3-C7-cycloalkyl-C1-C4-alkyl, where the C3-C7-cycloalkyl groups in the two aforementioned radicals are unsubstituted or partially or completely halogenated, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C1-C4-alkoxy-C1-C4-alkyl, phenyl and benzyl, where phenyl and benzyl are unsubstituted or substituted by 1, 2, 3 or 4 groups, which are identical or different and selected from the group consisting of halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy and C1-C4-haloalkoxy; Rh is selected from the group consisting of hydrogen, C1-C6-alkyl, C3-C7-cycloalkyl, C3-C7-cycloalkyl-C1-C4-alkyl, where the C3-C7-cycloalkyl groups in the two aforementioned radicals are unsubstituted or partially or completely halogenated, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C1-C4-alkoxy-C1-C4-alkyl, a radical C(═O)—Rk, phenyl and benzyl, where phenyl and benzyl are unsubstituted or substituted by 1, 2, 3 or 4 groups, which are identical or different and selected from the group consisting of halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy and C1-C4-haloalkoxy, R2g, R2h independently of each other have the meanings given for Rg, Rh; Rk has the meanings given for Rc; an N-oxide or an agriculturally suitable salt thereof.
地址 Ludwigshafen DE