摘要 |
Novel esters in all possible isomeric forms or a mixture thereof having the formula <IMAGE> I wherein Y is selected from the group consisting of hydrogen, halogen, -OAlK and <IMAGE> AlK is alkyl of 1 to 6 carbon atoms, n is 0, 1 or 2, Z is selected from the group consisting of -O- and -S-, R1 is selected from the group consisting of (a) optionally unsaturated alkyl of 1 to 8 carbon atoms and optionally unsaturated cycloalkyl or cycloalkylalkyl of 3 to 8 carbon atoms optionally substituted with at least one member of the group consisting of halogen, -OH, -SH, -OR', -SR', <IMAGE> +TR <IMAGE> -SO2AlK2, -SO3AlK3, aryl optionally substtuted with at least one member of the group consisting of -OH, alkoxy of 1 to 8 carbon atoms, alkyl of 1 to 8 carbon atoms, halogen, -CF3, -OCF3, -SCF3 and <IMAGE> R' is alkyl of 1 to 8 carbon atoms, R'' and R''' are individually selected from the group consisting of hydrogen and alkyl of 1 to 8 carbon atoms, AlK1, AlK2 and AlK3 are individually alkyl of 1 to 18 carbon atoms (b) aryl of 6 to 14 carbon atoms optionally substituted with at least one substituent selected from the group consisting of -OH, alkoxy of 1 to 8 carbon atoms, alkyl of 1 to 8 carbon atoms, halogen, -OCF3, -CF3 and -SCF3 and (c) heterocycle optionally substituted with at least one member of the group consisting of -OH, alkoxy of 1 to 8 carbon atoms, alkyl of 1 to 8 carbon atoms, halogen, -CF3, -OCF3 and -SCF3, R2, R3 and R4 are individually selected from the group consisting of hydrogen, halogen, alkyl of 1 to 8 carbon atoms, haloalkyl of 1 to 8 carbon atoms containing a plurality of halogens and alkoxy of 1 to 8 carbon atoms, W is selected from the group consisting of hydrogen and -CN, X is selected from the group consisting of carbon and nitrogen, Ar is selected from the group consisting of optionally substituted phenyl, pyridyl, thienyl, naphthyl, furyl and pyrrolyl and the ethylenic double bond may have Z or E geometry having parasitic activity, especially insecticidal, acaricidal and nematocidal activity.
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