摘要 |
1,193,346. Aldehydes derived from hexahydropyrimidine-2-ones and 2-thiones. BADISCHE ANILIN- & SODA-FABRIK A.G. 14 Sept. 1967 [15 Sept. 1966] No. 41970/67. Heading C2C. Aldehydes (I) are prepared by reacting the methylol compounds (II) with about the stoichiometric amount of HCR<SP>7</SP>R<SP>8</SP>CHO, at 0-120‹ C. in presence of an acid In the above formulµ, X is O or S, R<SP>1</SP> is H, alkyl or CR<SP>7</SP>R<SP>8</SP>CHO R<SP>2</SP> . . . R<SP>6</SP> are H or alkyl, R<SP>7</SP> and R<SP>8</SP> are alkyl, R<SP>9</SP> is H or-when R<SP>6</SP> is alkyl-R<SP>9</SP> is the same alkyl group, and R<SP>10</SP> is H, alkyl or CH 2 OR<SP>9</SP>. |