METHOD OF PREPARING 1-BUTYL-2-MAGNESIUMBUTYLFULLERENES(60)

摘要

FIELD: organic synthesis. SUBSTANCE: method consists in interaction of toluene solution of fullerene(60) with excess of ether solution dibutylmagnesium in presence of zirconacene dichloride as catalyst in quantity 1-3 mol % based on amount of dibutylmagnesium. Reaction is conducted for 12 hr under argon atmosphere and normal conditions at fullerene-to- dibutylmagnesium molar ratio from 1:35 to 1:90. Products can find use organic or organometallic syntheses. EFFECT: extended synthetic possibilities. 1 tbl