发明名称 PROCESS FOR PREPARING HALOGEN-SUBSTITUTED ORGANOSILICON COMPOUNDS
摘要 FIELD: chemistry of organosilicon compounds. SUBSTANCE: object of the claimed invention is attained by hydroxylation of halogen-methyl derivatives of bicyclo [2.2.1]heptene-5 with hydride-containing oligomethyl siloxanes in the presence of acid at temperature form 120 to 130 C according to the following scheme:. Use of the claimed process makes it possible to prepare linear and branched halogen alkyl substituted oligoorganosiloxanes using simplified procedure. This makes it possible to increase the yield of halogen alkyl substituted oligoorganosiloxanes by two times as compared with prior art. EFFECT: simplified technological process for preparation of halogen alkyl substituted linear and branched oligoorganosiloxanes and increased yield of the final products.
申请公布号 RU94027005(A) 申请公布日期 1996.08.10
申请号 RU19940027005 申请日期 1994.07.18
申请人 INSTITUT EHLEMENTOORGANICHESKIKH SOEDINENIJ IM. A.N.NESMEJANOVA RAN;ROSSIJSKIJ KHIMIKO-TEKHNOLOGICHESKIJ UNIVERSITET IM. D.I.MENDELEEVA 发明人 ZAVIN B.G.;KIREEV V.V.;ASTRINA V.I.;PILIPKOVA A.JU.
分类号 C07F7/12 主分类号 C07F7/12
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