Process for crystallization of polyethylene naphthalate.

摘要

High molecular weight polyester resins are sometimes produced from low molecular weight polyester prepolymers having the same composition by solid state polymerization. Polyester prepolymers are generally converted from the amorphous state to the crystalline state prior to solid state polymerization in order to raise their sticking temperature. This is done to keep the polyester prepolymer from sticking together as a solid mass in the solid state polymerization reactor. Such polyester prepolymers are traditionally crystallized by simply heating them to an elevated temperature at which crystallization occurs. However, polyethylene naphthalate prepolymer cannot be crystallized by utilizing this simply traditional approach. This inventions discloses a process for crystallizing amorphous polyethylene naphthalate prepolymer which comprises: (1) heating the amorphous polyethylene naphthalate prepolymer to a temperature which is within the range of about 80 DEG C to about 140 DEG C in the presence of a stream of an inert gas or under a vacuum to devolatilize the amorphous polyethylene naphthalate prepolymer; and (2) subsequently heating the devolatilized polyethylene naphthalate prepolymer to a temperature which is within the range of about 150 DEG C to about 260 DEG C while providing agitation to produce the crystallized polyethylene naphthalate prepolymer.