| 摘要 |
1,263,708. Linear polyamides. IMPERIAL CHEMICAL INDUSTRIES Ltd. 17 Oct., 1969 [28 Oct., 1968], No. 51087/68. Heading C3R. Synthetic linear melt-spinnable polyamides or copolyamides made from dibasic acid and diamine, having increased # rel , are made by a process comprising the incorporation into a molten polyamide of at least one di- or polyaryl ester of a C 5-36 dicarboxylic acid. In the acid, the COOH gps. are attached either to separate C-atoms other than vicinal- or peripositioned C-atoms, or to a single C-atom, whose other bonds are either connected to saturated aliphatic groups or form part of a saturated alicyclic structure. The amount of ester is stoichiometrically equivalent to the free amine end-groups in polyamide P. The time from the incorporation of ester to the solidification of the spun product is such as to give the optimum rise of # rel in the spun product. The acid may be aliphatic, cycloaliphatic, aromatic, or heterocyclic optionally containing -O-, -S-, -N-, -CO-, or amide groups as part of its structure. The ester may be diphenyl or dicresyl adipate. Many examples of acid and ester are listed. The incorporation of ester may be by coating chips of polyamide with the ester; or by adding ester to polyamide as a master-batch; the ester may first be pelletized with an inert binder. The polyamide may be made in a continuous polymerization process; it may be nylon 6,6 and may have various values of # rel , AEG, and CEG. Also present may be #60 parts Cu, e.g. as Cu acetate and #600 parts I, e.g. as KI, per million parts polyamide. 22 p.p.m. B as NaBO 2 may also be present, # rel may be #50, and heat-strength retention may be #90%. |
