发明名称 Photoinitiators
摘要 The present invention provides novel photoinitiators for polyurethane formation, in which a photoinitiator moiety and a tertiary amine are incorporated into the photoinitiator structure, and thus the polyurethane polymer.
申请公布号 US9399633(B2) 申请公布日期 2016.07.26
申请号 US201514938896 申请日期 2015.11.12
申请人 Coloplast A/S 发明人 Madsen Niels Joergen;Sehnal Petr;Nielsen Christian B.;Anderson David George
分类号 C07D335/16;C07D207/416;C08F2/50;C08G18/32;C08G18/48;C08G18/50;C08G18/73;C08G18/75;C07C217/22;C07C225/16;C07C225/22;C08J3/24;C08J3/28;C09D175/12;C07C213/02;C07C221/00;C07C217/62 主分类号 C07D335/16
代理机构 Coloplast Corp., Coloplast A/S 代理人 Coloplast Corp., Coloplast A/S ;Baumann Nick
主权项 1. A photoinitiator of the formula (I): in which: Pi is With Za attached in para position to the chlorine atom; Za and Zb together form a single bond, or a linker in which Za is selected from optionally substituted —(O—(C1-C12 alkylene))n-, optionally substituted —(NR1—(C1-C12 alkylene))n wherein R1 is H or optionally substituted C1-C12 alkyl and optionally substituted —(S—(C1-C12 alkylene))n-; wherein n is 1; wherein Za is joined to Pi via the O, N or S atom in Za; and Zb is a single bond; X1 and X2 are independently selected from optionally substituted C1-C12 alkylene, optionally substituted C1-C12 alkenylene, optionally substituted heterocyclyl, —O—, —S—, —NR2—, —C(═O)—, —C(═NR2)—, —Si(R2)2—O—, optionally substituted aryl, and combinations thereof, wherein R2 is H or optionally substituted C1-C12 alkyl; wherein X1 and X2 may be linked to one another or to Za to form one or more ring structures; wherein Za, X1 and X2 are selected such that N is a tertiary amine; W1 and W2 are independently selected from the group consisting of —OH, —NH2, —NHR3 and —SH, wherein R3 is an optionally substituted C1-C12 alkyl.
地址 Humlebaek DK