发明名称 CONTINUOUS PREPARATION OF (METH)ACRYLIC ACID ALKYL ESTERS.
摘要 The present invention discloses a process for continuous preparation of (meth)acrylic acid alkyl esters by reacting (meth)acrylic acid with monohydric alkanols having from 1 to 8 carbon atoms in the presence of an acid esterification catalyst in a reaction zone, a product mixture is removed which comprises the resulting alkyl (meth)acrylate, the catalyst, and by-products formed during the course of esterification having higher boiling temperatures than that of alkyl (meth)acrylate, and from which alkyl (meth)acrylate is separated by distillation in a separation zone. The product mixture removed from the reaction zone is fed to a rectification unit (I), and separated therein by rectification in at least one product (I) comprising (meth)acrylic acid alkyl ester, and a product (II) comprising the catalyst; product (I) is fed to an additional rectification unit (II) and (meth)acrylic acid alkyl ester is separated therein by rectification.
申请公布号 MX9700897(A) 申请公布日期 1997.08.30
申请号 MX19970000897 申请日期 1997.02.04
申请人 BASF AKTIENGESELLSCHAFT 发明人 GABRIELE IFFLAND;ALBRECHT DAMS;ALEXANDER WECK;HEINRICH AICHINGER;HOLGER HERBST;GERHARD NESTLER;HERBERT EXNER;WILLI SCHMIDT;MATTHIAS GEISENDORFER
分类号 B01J27/02;B01J31/02;C07B61/00;C07C67/08;C07C67/54;C07C69/54;(IPC1-7):C07C69/54 主分类号 B01J27/02
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