发明名称 |
PROCESS FOR THE PRODUCTION OF ALKYL-ISOTHIOCYANIC ESTERS |
摘要 |
Alkyl-isothiocyanic esters having the formula R-N=C=S can be produced by reacting N-alkyl dithiocarbaminates with hydrogen peroxide in aqueous phase at 95 to 130.degree.C. According to the present invention the aqueous N-alkyl dithiocarbaminate solution is reacted with a 20 to 40% by weight aqueous hydrogen peroxide solution in a volume ratio of 1:0.8 to 1 while maintaining a pH value of 1.5 to 4.5. The solutions are preferably sprayed into a reactor while alkylisothiocyanate formed is distilled off in the form of a vapour and the aqueous phase containing the by-products accumulates in the reactor. By means of the process according to the present invention the space-time yield could be increased significantly while, as compared with the conventional process that is carried out at pH 5 to 9, the amount of sulphur formed is substantially reduced and the shut off times for cleaning the reactor can be minimized.
|
申请公布号 |
CA2034210(C) |
申请公布日期 |
1996.04.23 |
申请号 |
CA19912034210 |
申请日期 |
1991.01.15 |
申请人 |
MANUFACTURE LANDAISE DE PRODUITS CHIMIQUES |
发明人 |
GIESSELMANN, GUENTER;GUENTHER, KURT |
分类号 |
C07C331/20;(IPC1-7):C07C331/20 |
主分类号 |
C07C331/20 |
代理机构 |
|
代理人 |
|
主权项 |
|
地址 |
|