发明名称 ALKOXYLATION OF 2,2'-DIHYDROXY-1,1'-DINAPHTHTYL COMPOUND
摘要 PURPOSE:To enable industrially advantageous alkoxylation of the title compound in the shortened reaction time, easily in low costs, by selecting the solvent in case of a specific aprotic solvent in the presence of a potassium base, especially potassium carbonate. CONSTITUTION:In the presence of at least one base selected from potassium bases of K-R<4> (R<4> is 1 to 4 C alkoxy, -NH2, H), preferably a potassium alkoxide, and potassium carbonate, the compound of formula I is alkoxylated with an alkoxylating agent of the formula: R<1>-X (X is Cl, Br, I) such as methyl chloride in the aprotic solvent which has O or N atoms in its molecule and boils over 65 deg.C (preferably tetrahydrofuran and N-N-dimethylformamide or dimethyl sulfoxide are employed, when potassium carbonate is used as a base) to give a compound of formula II (R<1> is 1 to 18C hydrocarbon group).
申请公布号 JPH02101035(A) 申请公布日期 1990.04.12
申请号 JP19880253305 申请日期 1988.10.07
申请人 AGENCY OF IND SCIENCE & TECHNOL;DAICEL CHEM IND LTD 发明人 ICHIDA AKITO;TACHIBANA KOZO;SHINPO TOSHIO;YAMAGUCHI TOMOHIKO
分类号 B01J27/232;B01J27/24;B01J31/02;C07B61/00;C07C41/00;C07C41/16;C07C43/20;C07C43/215;C07C67/00 主分类号 B01J27/232
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