发明名称 PRODUCTION OF AMIDAMINE OXIDE COMPOUND EXCELLENT IN STABILITY AND SURFACE ACTIVE COMPOSITION DERIVED FROM THE SAME COMPOUND
摘要 PROBLEM TO BE SOLVED: To produce the subject compound excellent in stability of color tone and fragrance with the passage of time at low cost by oxidizing an amidamine compound in the presence of a specific organic phosphonic acid compound. SOLUTION: The objective compound is produced by reacting (A) an amidamine compound of formula I [R<3> is a (substituted by hydroxy) 7-21C alkyl or alkeny; R<4> and R<5> are each a (substituted by hydroxyl) 1-5C alkyl or alkenyl; (n) is 1-5] (e.g. N,N-dimethylaminopropyloctylamide) with (B) hydrogen peroxide in a quantity of >=110 mole % of stoichiometric one based on the quantity of the amidamine compound. The reaction is conducted in the presence of an organic phosphonic acid of formula II (R<1> is H or a 1-3C alkyl; M<1> , M<2> , M<3> and M<4> are each H or an alkali metal atom) in a quantity of 0.1-1.5 mole % based on the mole quantity of the charged amidamine compound, and at 40-100 deg.C (preferably at 60-l00 deg.C).
申请公布号 JPH11152260(A) 申请公布日期 1999.06.08
申请号 JP19980255339 申请日期 1998.09.09
申请人 KAWAKEN FINE CHEM CO LTD 发明人 MORITA HIDEO;CHIBA YOKO
分类号 B01J31/02;C07B61/00;C07C291/04;C11D1/75;C11D3/36 主分类号 B01J31/02
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