发明名称 Thermo-oxidatively stable, side chain polyether functionalized polynorbornenes for microelectronic and optoelectronic devices and assemblies thereof
摘要 The present invention relates to polynorbornene (PNB) composition embodiments that are useful for forming microelectronic and/or optoelectronic devices and assemblies thereof, and more specifically to compositions encompassing PNBs having norbornene-type repeating units that are polyether functionalized and an additive package containing a phenolic antioxidant and a synergist, and the microelectronic and/or optoelectronic devices made therefrom are resistant to thermo-oxidative chain degradation of said polyether functionalization.
申请公布号 US9425404(B2) 申请公布日期 2016.08.23
申请号 US201313741809 申请日期 2013.01.15
申请人 PROMERUS, LLC;SUMITOMO BAKELITE CO., LTD. 发明人 Apanius Christopher;Bell Andrew;Burns Cheryl;Cyrus Crystal;Elce Edmund;Groff Royce;Kaiti Sridevi;Knapp Brian;Ng Hendra;Ohashi Seishi;Zhang Wei
分类号 H01L51/00;C08F232/08;G03F7/039;G03F7/022;G03F7/023;G03F7/038 主分类号 H01L51/00
代理机构 代理人 Gupta Balaram
主权项 1. A microelectronic or optoelectronic device comprising one or more of a redistribution layer (RDL) structure, a chip stack structure, a CMOS image sensor dam structure, where said structures further comprise a positive tone, self imagable composition, which contains a thermo-oxidatively stabilized polymer having repeating units derived from a norbornene-type monomer in accordance with Formula A: where s is selected from 0 to 3, t is 2, u is an integer from 1 to 3 and R5 is selected from methyl, ethyl, n-propyl or i-propyl, and an additive package comprising one or more phenolic antioxidant selected from the group consisting of: 2,2′-((2-hydroxy-5-methyl-1,3-phenylene)bis(methylene))bis(4-methylphenol), 6,6′-methylenebis(2-(2-hydroxy-5-methylbenzyl)-4-methylphenol), 6,6′-2-hydroxy-5-methyl-1,3-phenylene)bis(methylene)bis(2-(2-hydroxy-5-methylbenzyl)-4-methylphenol), 6,6′-methylenebis(2-(2-hydroxy-3,5dimethylbenzyl-4-methylphenol), and 6,6′-(2-hydroxy-5-methyl-1,3-phenylene)bis(methylene)bis(2,4-dimethyphenol); and one or more diaryl amine synergist selected from the group consisting of: N,N′-di-2-naphthyl-p-phenylenediamine, bis(4-(tert-butyl)phenyl)amine, bis(4-(2-phenylpropan-2-yl)phenyl)amine, bis(4-(2,4,4-trimethylpentan-2-yl)phenyl)amine and bis(4-(2,4,4-trimethylpentyl)phenyl)amine; and wherein each of said antioxidant and amine synergist is present in an amount from 3 to 10 parts per hundred parts of said polymer.
地址 Brecksville OH US