发明名称 METHOD OF PREPARING ALPHA, BETA-DIFLUOROACRYLIC COMPOUNDS
摘要 The invention relates to a method of preparing alpha , beta -difluoroacrylic acid and alpha , beta -alkyl difluoroacrylates. The inventive method consists in: preparing 2,3-difluoro-2,3-dichloropropanol (I) by radical telomerisation of CFCl=CFCl with CH3OH; oxidising (I) in order to obtain 2,3-difluoro-2,3-dichloropropanoic acid (II); and treating (II) with Zn in order to dechlorinate and, optionally, esterify the acid function before or after the dechlorination step.
申请公布号 WO2004081169(A2) 申请公布日期 2004.09.23
申请号 WO2004FR00482 申请日期 2004.03.02
申请人 CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE;ECOLE NATIONALE SUPERIEURE DE CHIMIE DE MONTPELLIER;AMEDURI, BRUNO;BOUTEVIN, BERNARD;GUIOT, JEROME 发明人 AMEDURI, BRUNO;BOUTEVIN, BERNARD;GUIOT, JEROME
分类号 C07C51/27;C07C51/377;C07C67/14 主分类号 C07C51/27
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