发明名称 METHOD OF PRODUCING O-ALKENYL PHENOLS AND CATALYST FOR ITS IMPLEMENTATION
摘要 FIELD: chemistry.SUBSTANCE: invention relates to a method of producing o-alkenyl phenols, which are promising initial compounds for synthesis of medicinal preparations and fragrance compounds in cosmetic and food industries. Method involves reaction of phenol or substituted phenol with aliphatic aldehyde in presence of catalyst, which has general formula: xM O·yM O·zMO·qM/ carrier, where: Mis transition metal selected from row: Co, Cu, Ni, V, Mn, Cr; Mis metal of first group from row: Li, Na, K, Rb, Cs; Mis metal of third or fourth group from row: Zr, Ti, Ge and/or Ce, and/or U; Mis noble metal from row: Pt, Pd, Ru, Rh, Ag, Au; x, y, z, q are weight fractions of corresponding components, where x=0.0-0.50; y=0.0-0.05; z=0.0-0.05; q=0.0-0.2, by reaction:,where: X-X=-H, -Alc, -OH, -OAlc, -Hal; R=-H, hydrocarbon radical. Invention also relates to catalyst for producing o-alkenyl phenols.EFFECT: presented invention enables to obtain desired products with high output using simple technology.7 cl, 20 ex
申请公布号 RU2591954(C1) 申请公布日期 2016.07.20
申请号 RU20150108262 申请日期 2015.03.10
申请人 FEDERALNOE GOSUDARSTVENNOE BYUDZHETNOE UCHREZHDENIE NAUKI INSTITUT KATALIZA IM. G.K. BORESKOVA SIBIRSKOGO OTDELENIYA ROSSIJSKOJ AKADEMII NAUK 发明人 PARFENOV MIKHAIL VLADIMIROVICH;PIRYUTKO LARISA VLADIMIROVNA;KHARITONOV ALEKSANDR SERGEEVICH;STAROKON EVGENIJ VLADIMIROVICH;PAKHOMOV NIKOLAJ ALEKSANDROVICH;SOSHNIKOV IGOR EVGENEVICH;NOSKOV ALEKSANDR STEPANOVICH;PANOV GENNADIJ IVANOVICH
分类号 C07C37/20;B01J23/22;B01J23/26;B01J23/34;B01J23/42;B01J23/46;B01J23/75;B01J29/076;C07C39/19 主分类号 C07C37/20
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