发明名称 Method for producing hydrogen or heavy hydrogens, method for producing hydrogenated (protiated, deuterated or tritiated) organic compound, method for hydrogenating (protiating, deuterating or tritiating) organic compound, method for dehalogenating organic compound having halogen, and ball for use in mechanochemical reaction
摘要 Objects are to provide efficient methods for producing hydrogen or heavy hydrogens and for hydrogenating (protiating, deuterating or tritiating) an organic compound, and to provide an equipment and the like used therefor. A method for producing hydrogen or heavy hydrogens, containing subjecting water or heavy water to mechanochemical reaction in the presence of a catalyst metal, in which an energy density of a rotational acceleration of 75 G or more is applied to water or heavy water for 25 minutes or more, a method for producing a hydrogenated (protiated, deuterated or tritiated) organic compound, a method for hydrogenating (protiating, deuterating or tritiating) an organic compound, a method for dehalogenating an organic compound having halogen, and a ball for mechanochemical reaction are provided.
申请公布号 US9371272(B2) 申请公布日期 2016.06.21
申请号 US201314378877 申请日期 2013.02.08
申请人 Shiono Chemical Co., Ltd. 发明人 Sajiki Hironao;Monguchi Yasunari;Sawama Yoshinari;Kondo Shinichi;Sasai Yasushi
分类号 C07C221/00;C07C67/317;C07C213/02;C07C51/377;C01B3/02;B01J37/00;C01B3/04;C01B4/00;C07C5/05;C07C51/347;C07C69/78;C07B31/00;C07C5/08;C07C5/09;B01J23/06;B01J23/26;B01J23/755;B01J23/02;B01J23/42;B01J23/44;B01J23/46 主分类号 C07C221/00
代理机构 Oblon, McClelland, Maier & Neustadt, L.L.P 代理人 Oblon, McClelland, Maier & Neustadt, L.L.P
主权项 1. A method for producing hydrogen or heavy hydrogens, the method comprising: subjecting water or heavy water to a mechanochemical reaction with a planetary ball mill in the presence of a catalyst metal, wherein an energy density of a rotational acceleration of 75 G or more is applied to the water or heavy water for 25 minutes or more, and a conversion rate of water or heavy water to hydrogen or heavy hydrogen is 60% or more.
地址 Tokyo JP