| 主权项 |
1. A conductive covalent-organic framework (COF) comprising:
a plurality of cores, wherein each core forms at least one covalent bond to at least one linking moiety; and wherein at least one core of the plurality of cores comprises a conductive core moiety and/or wherein at least one linking moiety comprises a conductive linking moiety and wherein the core is selected from the group consisting of Formula I, II, III, IV, and V: wherein: R1-R59 are independently selected from the group consisting of H, D, FG, (C1-C20)alkyl, substituted (C1-C20)alkyl, (C1-C20)alkenyl, substituted (C1-C20)alkenyl, (C1-C20)alkynyl, substituted (C1-C20)alkynyl, hetero-(C1-C20)alkyl, substituted hetero-(C1-C20)alkyl, hetero-(C1-C20)alkenyl, substituted hetero-(C1-C20)alkenyl, hetero-(C1-C20)alkynyl, substituted hetero-(C1-C20)alkynyl, (C1-C20)cycloalkyl, substituted (C1-C20)cycloalkyl, aryl, substituted aryl, heterocycle, substituted heterocycle, wherein R5 and R6 are linked together to form a substituted or unsubstituted ring selected from the group consisting of cycloalkyl, aryl and heterocycle, wherein R7 and R8 are linked together to form a substituted or unsubstituted ring selected from the group consisting of cycloalkyl, aryl and heterocycle, wherein R9 and R10 are linked together to form a substituted or unsubstituted ring selected from the group consisting of cycloalkyl, aryl and heterocycle, and wherein R11 and R12 are linked together to form a substituted or unsubstituted ring selected from the group consisting of cycloalkyl, aryl and heterocycle; X1-X13 are independently selected from the group consisting of carbon, oxygen, sulfur, silicon, phosphorous, and nitrogen; Y1-Y7 are independently selected from the group consisting of H, D, and FG; A1-A27 are independently selected from the group consisting of C, N, Si and P; with the proviso that a X may not exceed its maximum valence by binding a Y, or R1-R4; and with the proviso that a A may not exceed its maximum valence by binding a R. |
