Verfahren zur Herstellung eines modifizierten Polyethylen in einem Extruder

摘要

The present invention relates to a process for modifying a polyethylene in an extruder. The polyethylene is brought into contact with oxygen or a gas mixture containing oxygen in the extruder, optionally in the presence of a relatively small quantity or preferably in the absence of short-term antioxidant agent. The polyethylene thus brought into contact is treated thermomechanically in the molten state in the extruder supplying a relatively high specific mechanical energy, the treatment being conducted to its term when the value of the loss tangent of the polyethylene characterizing its viscoelastic state decreases with a desired proportion. The polymer thus treated is particularly suitable for being transformed into film by blown extrusion with a considerably increased bubble stability.