发明名称 METHOD FOR PRODUCING STERILIZED MEDICAL FORMED ARTICLE
摘要 A method is disclosed for producing a sterilized medical formed article that includes applying high-energy rays to a medical formed article at an exposure E. The medical formed article is formed of a resin composition that includes a hydrogenated block copolymer and a phenol-based antioxidant. The hydrogenated block copolymer is obtained by hydrogenating 99% or more of unsaturated bonds of a block copolymer that includes at least two polymer blocks [A] and at least one polymer block [B], the polymer block [A] including a repeating unit derived from an aromatic vinyl compound as a main component, the polymer block [B] including a repeating unit derived from a linear conjugated diene compound as a main component, and a ratio (wA:wB) of a weight fraction wA of the polymer block [A] to a weight fraction wB of the polymer block [B] being 30:70 to 70:30.
申请公布号 US2016213796(A1) 申请公布日期 2016.07.28
申请号 US201414914363 申请日期 2014.08.29
申请人 ZEON CORPORATION 发明人 KOHARA Teiji;ISHIGURO Atsushi
分类号 A61L2/08 主分类号 A61L2/08
代理机构 代理人
主权项 1. A method for producing a sterilized medical formed article comprising applying high-energy rays to a medical formed article at an exposure E, the medical formed article being formed of a resin composition that comprises a hydrogenated block copolymer and a phenol-based antioxidant, the hydrogenated block copolymer being obtained by hydrogenating 99% or more of unsaturated bonds of a block copolymer that comprises at least two polymer blocks [A] and at least one polymer block [B], the polymer block [A] comprising a repeating unit derived from an aromatic vinyl compound as a main component, the polymer block [B] comprising a repeating unit derived from a linear conjugated diene compound as a main component, and a ratio (wA:wB) of a weight fraction wA of the polymer block [A] in the block copolymer to a weight fraction wB of the polymer block [B] in the block copolymer being 30:70 to 70:30, and the resin composition comprising the phenol-based antioxidant in a ratio of W to 0.50 parts by weight based on 100 parts by weight of the hydrogenated block copolymer, W being calculated by an expression (1), W=[0.46×(100−H)+0.04]×(E/25)  (1)where, W is the ratio (parts by weight) of the phenol-based antioxidant based on 100 parts by weight of the hydrogenated block copolymer, H is the hydrogenation rate (%) of the hydrogenated block copolymer, H is a numerical value from 99 to 100, and E is the exposure (kGy) of the high-energy rays.
地址 Tokyo JP