Rapid fabrication of hierarchically structured supramolecular nanocomposite thin films in one minute

摘要

Functional nanocomposites containing nanoparticles of different chemical compositions may exhibit new properties to meet demands for advanced technology. It is imperative to simultaneously achieve hierarchical structural control and to develop rapid, scalable fabrication to minimize degradation of nanoparticle properties and for compatibility with nanomanufacturing. The assembly kinetics of supramolecular nanocomposite in thin films is governed by the energetic cost arising from defects, the chain mobility, and the activation energy for inter-domain diffusion. By optimizing only one parameter, the solvent fraction in the film, the assembly kinetics can be precisely tailored to produce hierarchically structured thin films of supramolecular nanocomposites in approximately one minute. Moreover, the strong wavelength dependent optical anisotropy in the nanocomposite highlights their potential applications for light manipulation and information transmission. The present invention opens a new avenue in designing manufacture-friendly continuous processing for the fabrication of functional nanocomposite thin films.

主权项

1. A method of forming a supramolecular nanocomposite thin film comprising:
mixing a block copolymer polystyrene-b-poly-4-vinylpyridine (PS-b-P4VP) with 3-pentadecylphenol (PDP) and nanoparticles in a solution; spin-coating the mixed solution onto a substrate; and solvent annealing the thin film by injecting chloroform (CHCl3) solvent, wherein the amount of solvent infected is varied from approximately 0.01 to 5 mL to control a swelling rate of the thin film.