发明名称 |
Process for the production of cyclohexanedimethanol |
摘要 |
A process is described for the production of cyclohexanedimethanol having a trans-:cis-isomer ratio greater than about 1:1 by hydrogenation of a dialkyl (e.g. dimethyl) cyclohexanedicarboxylate having a trans-:cis-isomer ratio less than about 1:1 which comprises: (a) providing a hydrogenation zone containing a charge of a granular heterogeneous ester hydrogenation catalyst; (b) supplying to the hydrogenation zone a vaporous feed stream containing hydrogen and a hydrogenarable material comprising a dialkyl cyclohexanedicarboxylate at an inlet temperature which is above its dew point of the mixture; (c) maintaining the hydrogenation zone under temperature and pressure conditions which are conducive to effecting hydrogenation of esters; (d) passing the vaporous feed stream through the hydrogenation zone; and (e) recovering from the hydrogenation zone a product stream containing cyclohexanedimethanol having a trans-:cis-isomer ratio greater than 1:1. In this process it is preferred to use dimethyl 1,4-cyclohexanedicarboxylate to produce 1,4-cyclohexanedimethanol.
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申请公布号 |
US5395986(A) |
申请公布日期 |
1995.03.07 |
申请号 |
US19930174314 |
申请日期 |
1993.12.30 |
申请人 |
EASTMAN CHEMICAL COMPANY |
发明人 |
SCARLETT, JOHN;WOOD, MICHAEL A. |
分类号 |
B01J23/42;B01J23/44;B01J23/60;B01J23/72;B01J23/86;B01J23/889;C07B53/00;C07B61/00;C07C29/149;C07C31/27;(IPC1-7):C07C31/27 |
主分类号 |
B01J23/42 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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