METHOD FOR THE PRODUCTION OF POLYMERS AND OLIGOMERS CONJUGATED WITH HIGH SOLUBILITY LATERAL ALCOXY AND HYDROXYL GROUPS, HAVING PHOTOLUMINESCENT AND SEMICONDUCTING PROPERTIES THROUGH CROSSED ALDOL CONDENSATION BETWEEN AROMATIC DIALDEHYDES AND ALKOXYKETONE GENERATED IN SITU BY THE WILLIAMSON REACTION BETWEEN HYDROXYKETONES AND HALOALKANES.

摘要

The present disclosure is related to a method used to modify conjugated polymers obtained by crossed aldol condensation from aromatic dialdehydes and mixtures of ketones, alkoxy ketones and haloalkanes generated in-situ by the Williamson reaction from hydroxyketones and haloalkanes; the resulting materials have photoluminescence and electroluminescence properties, as well as high solubility. Thereby, facilitating processing and being potentially suitable for use in the microelectronics and nanotechnology areas, as well as in optoelectronics, sensors and actuators, inter alia.