| 摘要 |
In various embodiments, the invention provides electro-chemical processes for reduction of carbon dioxide, for example converting carbon dioxide to format salts or formic acid. In selected embodiments, operation of a continuous reactor with a three dimensional cathode and a two-phase (gas/liquid) catholyte flow provides advantages conditions for electro-reduction of carbon dioxide. In these embodiments, the continuous two-phase flow of catholyte solvent and carbon dioxide containing gas, in selected gas/liquid phase volume flow ratios, provides dynamic conditions that favour the electro-reduction of COs at relatively high effective superficial current densities and gas space velocities, with relatively low reactor (cell) voltages (<10 volts). In some embodiments, relatively high internal gas hold-up in the cathode chamber (evident in an internal gas to liquid phase volume ratio >0.1) may provide greater than equilibrium CO2 concentrations in the liquid phase, also facilitating relatively high effective superficial current densities. In some embodiments, these characteristics may for example be achieved at catholyte pH >7 and relatively low CO2 partial pressures (<10 bar). In some embodiments, these characteristics may for example be achieved under near adiabatic conditions, with catholyte outlet temperature up to about 80° C. |
