主权项 |
1. A method for cross-linking of an organic transition metal complex into a multi-dimensional network, comprising:
performing a first reaction which comprises:
a first reactant in the form of the organic transition metal complex; anda second reactant for formation of the multi-dimensional network; wherein the organic transition metal complex is cross-linked during the first reaction by formation of covalent bonds to form the multi-dimensional network; wherein the organic transition metal complex comprises at least two anchor groups of a first anchor group species for the covalent bonding of the organic transition metal complex into the multi-dimensional network and the second reactant comprises at least one anchor group of a second anchor group species; wherein the cross-linking of the organic transition metal complex proceeds by reaction of each of the at least two anchor groups of the organic transition metal complex with an anchor group of the second reactant; wherein the cross-linking is not a copolymerization, the copolymerization comprising a reaction in which a plurality of different monomers are cross-linked with each other; wherein the second reactant and the first reactant are different from each other; and wherein the second reactant is selected from the group consisting of an oligomer and a polymer wherein the first and the second anchor group species are selected from corresponding pairs of: R1-R6 can each independently be hydrogen, a halogen or substituents, which are bound via —OR*, —NR*2 or —SiR*3 as well as alkyl, aryl, heteroaryl, alkenyl, alkynyl groups or substituted alkyl, aryl, heteroaryl and alkenyl groups; R*=organic group selected from the group consisting of hydrogen, a halogen or deuterium, as well as alkyl, aryl, heteroaryl, alkenyl, alkynyl groups or substituted alkyl, aryl, heteroaryl and alkenyl groups; Wherein EWG is an electron withdrawing group. |