发明名称 ELECTRODE AND NONAQUEOUS ELECTROLYTE BATTERY
摘要 According to one embodiment, an electrode is provided. The electrode includes an electrode mixture layer and a current collector. The electrode mixture layer contains active material particles. The electrode mixture layer includes a first surface being in contact with the current collector and a second surface separated from the first surface by a thickness of the electrode mixture layer. The electrode mixture layer includes a first portion having the first surface and a second portion having the second surface. In the first portion, a first oxide layer is formed on the active material particle. In the second portion, a second oxide layer is formed on the active material particles. The thickness of the first oxide layer is more than the thickness of the second oxide layer.
申请公布号 US2016308202(A1) 申请公布日期 2016.10.20
申请号 US201615196732 申请日期 2016.06.29
申请人 KABUSHIKI KAISHA TOSHIBA 发明人 KURIYAMA Hiromichi;SARUWATARI Hidesato;SATAKE Hideki
分类号 H01M4/36;H01M4/525;H01M4/485;H01M10/0525;H01M4/131;H01M4/505;H01M4/58 主分类号 H01M4/36
代理机构 代理人
主权项 1. An electrode comprising: an electrode mixture layer comprising active material particles comprising Li and at least one transition metal selected from the group consisting of Fe, Mn, Co and Ni; and a current collector comprising at least one surface on which the electrode mixture layer is supported, wherein: the electrode mixture layer comprises a first surface being in contact with the current collector and a second surface separated by a thickness of the electrode mixture layer from the first surface; the electrode mixture layer comprises: a first portion having a thickness of at least 20% of the thickness of the electrode mixture layer and comprising the first surface; and a second portion having a thickness of at least 20% of the thickness of the electrode mixture layer and comprising the second surface; in the first portion of the electrode mixture layer, a first oxide layer is formed on surfaces of the active material particles, the first oxide layer comprising at least one element selected from the group consisting of Li, Mg, Ca, B, Al, Si, P, Fe, Mn, Co, Ni, Cu, Zn, Zr, Nb, Mo, Ta, and W, and having a thickness of more than 0.5 nm and 100 nm or less; in the second portion of the electrode mixture layer, a second oxide layer is formed on surfaces of the active material particles, the second oxide layer comprising at least one element selected from the group consisting of Li, Mg, Ca, B, Al, Si, P, Fe, Mn, Co, Ni, Cu, Zn, Zr, Nb, Mo, Ta, and W, and having a thickness of 0.5 nm or more and less than 100 nm; and the thickness of the first oxide layer is more than the thickness of the second oxide layer.
地址 Minato-ku JP