| 摘要 |
<p>A method for analyzing the heteroatom content of solid products which spatter, boil or bump under conditions involving rapid heating, such as Fischer-Tropsch heavy products, including Fischer-Tropsch waxes, is disclosed. The heteroatom content of Fischer-Tropsch heavy products can be determined by melting the sample prior to injecting into the analytical instrument used for the analysis. This provides results that are reproducible and accurate. The melting can be done, for example, prior to injection, in a syringe, or by placing the sample in a boat and melting in prior to injection. The melting can be effected by simply moving the boat slowly into the chamber which allows sufficient time for the sample to melt before it is exposed to the high temperature of the combustion zone. Nitrogen and sulfur determination are preferably carried out using a chemiluminescent detector that detects chemically-bound nitrogen and/or sulfur. Oxygen detection is preferably carried out using GC/MS.</p> |
