发明名称 |
Hydrothermal process for the production of LiFePO<sub>4 </sub>powder |
摘要 |
The present invention relates to a process for the production of LiFePO4 powder, comprising the steps: a) providing an aqueous solution of an organic surfactant; b) providing an aqueous solution of an iron (II) salt and mixing said aqueous iron (II) salt solution with an aqueous solution of a phosphate, to provide a mixed iron (II) salt/phosphate solution having a stoichiometric ratio of Fe2+:phosphate of about 1:1; c) adding the mixed iron (II) salt/phosphate solution to the surfactant solution under constant stirring; d) providing an aqueous solution comprising a lithium salt, adding said aqueous solution comprising a lithium salt to said mixed iron (II) salt/phosphate solution to provide a mixture having a stoichiometric ratio of Fe2+:phosphate:lithium salt of about 1:1:3 and stirring the resulting mixture; e) heating the resulting mixture at 80-200° C.; f) washing the resulting precipitate to remove excess surfactant, filtering and drying the precipitate; and g) heat treating the dried precipitate in an inert atmosphere by firing at 550-850° C. for at least 2 hours, wherein a co-solvent is added during or after any one of steps (a) to (d). |
申请公布号 |
US9484574(B2) |
申请公布日期 |
2016.11.01 |
申请号 |
US200913509203 |
申请日期 |
2009.11.10 |
申请人 |
Bodoardo Silvia;Gerbaldi Claudio;Meligrana Giuseppina;Di Lupo Francesca;Penazzi Nerino;Fontana Daniela |
发明人 |
Bodoardo Silvia;Gerbaldi Claudio;Meligrana Giuseppina;Di Lupo Francesca;Penazzi Nerino;Fontana Daniela |
分类号 |
H01M4/136;C01B25/45;H01M4/58;H01M10/0525;H01M4/1397 |
主分类号 |
H01M4/136 |
代理机构 |
Sterne, Kessler, Goldstein & Fox PLLC |
代理人 |
Sterne, Kessler, Goldstein & Fox PLLC |
主权项 |
1. A process for the production of LiFePO4 powder, comprising the steps:
a) providing an aqueous solution of an organic surfactant; b) providing an aqueous solution of an iron (II) salt and mixing said aqueous iron (II) salt solution with an aqueous solution of a phosphate, to provide a mixed iron (II) salt/phosphate solution having a stoichiometric ratio of Fe2+:phosphate of about 1:1; c) adding the mixed iron (II) salt/phosphate solution to the surfactant solution under constant stirring; d) providing an aqueous solution comprising a lithium salt, adding said aqueous solution comprising a lithium salt to said mixed iron (II) salt/phosphate solution to provide a mixture having a stoichiometric ratio of Fe2+:phosphate:lithium salt of about 1:1:3 and stirring the resulting mixture; e) heating the resulting mixture at 80-200° C.; f) washing the resulting precipitate to remove excess surfactant, filtering and drying the precipitate; and g) heat treating the dried precipitate in an inert atmosphere by firing at 550-850° C. for at least 2 hours, wherein a co-solvent is added during step (a) to provide a solution of organic surfactant in a mixture of water and co-solvent. |
地址 |
Turin IT |