Moisture curable organopolysiloxane compositions

摘要

The present invention provides curable compositions that are substantially free of metal catalysts including both tin and non-tin metal catalysts. The curable compositions employ a catalyst composition comprising the combination of a (i) carbodiimide functional compound, and (ii) an amino-containing compound such as an amino silane functional compound and/or an organic amine compound. The combination of these materials, particularly when aged, accelerates the condensation curing of moisture curable silicones/non-silicones even in the absence of a metal-based catalyst.

主权项

1. A composition for forming a cured polymer composition comprising:
(A) a polymer having at least a reactive silyl group; (B) a crosslinker or chain extender chosen from an alkoxysilane, an alkoxysiloxane, an oximosilane, an oximosiloxane, an enoxysilane, an enoxysiloxane, an aminosilane, a carboxysilane, a carboxysiloxane, an alkylamidosilane, an alkylamidosiloxane, an arylamidosilane, an arylamidosiloxane, an alkoxyaminosilane, an alkarylaminosiloxane, an alkoxycarbamatosilane, an alkoxycarbamatosiloxane, and combinations of two or more thereof; and (C) a catalyst composition comprising (i) a carbodiimide functional compound, and (ii) an amino silane functional compound, an organic amine, or a combination thereof wherein the catalyst composition is aged for at least one hour prior to addition to the curable composition.