发明名称 3-(acyloxyphenyl)benzofuran-2-one stabilizers
摘要 Compounds of the formula (1) <IMAGE> (1) in which R2, R3, R4 and R5, independently of one another, are hydrogen, C1-C25alkyl, C7-C9phenylalkyl, unsubstituted or C1-C4alkyl-substituted phenyl, unsubstituted or C1-C4-alkly-substituted C5-C8cycloalkyl; C1-C18alkoxy, hydroxyl, C1-C25alkanoyloxy, C3-C25alkenoyloxy, C3-C25alkanoyloxy which is interrupted by oxygen, sulfur or >N-R16; C6-C9cycloalkylcarbonyloxy, benzoyloxy or C1-C12alkyl-substituted benzoyloxy, where R16 is hydrogen or C1-C8alkyl, or, furthermore, the radicals R2 and R3 or the radicals R4 and R5 together with the carbon atoms to which they are bound form a phenyl ring, R4 is additionally -(CH2)n-COR11, in which n is 0, 1 or 2, R11 is hydroxyl, <IMAGE> C1-C18alkoxy or <IMAGE> R14 and R15, independently of one another, are hydrogen or C1-C18alkyl, M is an r-valent metal cation and r is 1, 2 or 3, R7, R8, R9 and R10, independently of one another, are hydrogen, C1-C4alkyl or C1-C4alkoxy, with the proviso that at least one of the radicals R7, R8, R9 and R10 is hydrogen and, in the case where R3, R5, R6, R7 and R10 are hydrogen, R4 is additionally a radical of the formula (2) <IMAGE> (2) in which R2, R8 and R9 are as defined above and R1 is as defined below for m=1, and R12 and R13, independently of one another, are hydrogen, C1-C12alkyl or phenyl, m is 1 or 2, and, in the case where m is 1, R1 is hydrogen, C1-C25alkanoyl, C3-C25alkenoyl, C3-C25alkanoyl which is interrupted by oxygen, sulfur or >N-R16; C6-C9cycloalkylcarbonyl, benzoyl or C1-C12alkyl-substituted benzoyl, R16 is as defined above and R6 is hydrogen or a radical of the formula (3) <IMAGE> (3) in which R1, R2, R3, R4, R5, R7, R8, R9 and R10 are as defined above, and, in the case where m is 2, R1 is <IMAGE> in which R17 is a direct bond, C1-C18alkylene, C2-C18alkylene which is interrupted by oxygen, sulfur or >N-R16; C2-C18alkenylene, C2-C20alkylidene, C7-C20phenylalkylidene, C5-C8cycloalkylene, C7-C8bicycloalkylene or phenylene, R16 is as defined above and R6 is hydrogen, are described as stabilizers for organic materials against oxidative, thermal or light-induced degradation.
申请公布号 US5369159(A) 申请公布日期 1994.11.29
申请号 US19930064191 申请日期 1993.05.17
申请人 CIBA-GEIGY CORPORATION 发明人 NESVADBA, PETER
分类号 C07D307/80;C07D307/83;C08K5/15;C08K5/1535;C08L101/00;(IPC1-7):C08K5/15;C09K15/06 主分类号 C07D307/80
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