发明名称 非水電解質二次電池
摘要 A non-aqueous electrolyte secondary battery having a positive electrode active material with excellent water resistance is provided. The non-aqueous electrolyte secondary battery includes a positive electrode containing positive electrode active material particles composed of a core section formed of olivine type LiFePO 4 ; an intermediate section that lies on the outer side of the core section and has a lithium iron phosphate that can be represented by the formula: LiFe x P y O z ; and a surface section that lies on the outer side of the intermediate section and has lithium iron phosphate that can be represented by the formula: LiFe a P b O c ; and a negative electrode containing lithium titanate, in which battery the molar concentration ratio of Fe relative to P of the lithium iron phosphate at the core section is greater than the average of the ratio x/y of LiFe x P y O z , the average value of the ratio a/b of LiFe a P b O c at the surface section of the positive electrode active material particles is smaller than the average of the ratio x/y of LiFe x P y O z , and the positive electrode active material particles include a region in which the ratio x/y of LiFe x P y O z at the intermediate section increases continuously or intermittently in the direction from the surface section toward the core section.
申请公布号 JP5981101(B2) 申请公布日期 2016.08.31
申请号 JP20110133555 申请日期 2011.06.15
申请人 株式会社東芝 发明人 松野 真輔;山本 大;佐竹 秀喜;高見 則雄
分类号 H01M10/0525;H01M4/36;H01M4/485;H01M4/58 主分类号 H01M10/0525
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