发明名称 Light emitting device and method of manufacturing thereof
摘要 A light emitting device includes a package having side walls which define a recess, a light emitting element arranged in the recess, and a sealing member which seals the light emitting element. The sealing member includes a first portion which contains a fluorescent material and covers the light emitting element, and a second portion which does not contain a fluorescent material and is arranged over the first portion. The fluorescent material is a fluoride fluorescent material activated with tetravalent manganese represented by the following formula (I). The particles of the fluorescent material has a surface region with a tetravalent manganese ion concentration is lower than inner side. A2[M1-bMn4+bF6]  (I) In the formula (I), A is a cation which contains K+ and may contain at least one selected from the group consisting of Li+, Na+, Rb+, Cs+, and NH4+, M is at least one of 15 Group 4 and Group 14 elements, and 0<b<0.2.
申请公布号 US9419187(B2) 申请公布日期 2016.08.16
申请号 US201514657676 申请日期 2015.03.13
申请人 NICHIA CORPORATION 发明人 Akagawa Seitaro;Yoshida Tomokazu
分类号 H01L29/15;H01L33/00;H01L33/50;C09K11/00;C09K11/61;C09K11/77 主分类号 H01L29/15
代理机构 Foley & Lardner LLP 代理人 Foley & Lardner LLP
主权项 1. A light emitting device comprising: a package having side walls which define a recess; a light emitting element arranged in the recess; and a sealing member which seals the light emitting element; wherein the sealing member comprises: a first sealing member portion covering the light emitting element, the first sealing member portion comprising a first binder portion, and fluorescent material particles located in the first binder portion, anda second sealing member portion covering the first sealing member portion, the second sealing member portion comprising a second binder portion, and substantially no fluorescent material particles located in the second binder portion, wherein the fluorescent material particles include particles of a fluoride fluorescent material that is activated with tetravalent manganese ions and has a chemical composition represented by the following formula (I), A2[M1-bMn4+bF6]  (I) wherein A is a cation which contains at least K+ and may further contain at least one selected from the group consisting of Li+, Na+, Rb+, Cs+, and NH4+, M is at least one element selected from the group consisting of Group 4 elements and Group 14 elements, and 0<b<0.2, and wherein the particles of fluoride fluorescent material include a surface region and an inner region, both the surface region and the inner region comprising tetravalent manganese ions, and wherein a tetravalent manganese ion concentration of the surface region of the particles of fluoride fluorescent material is lower than a tetravalent manganese ion concentration of the inner region of the particles of fluoride fluorescent material.
地址 Anan-Shi JP