发明名称 Optical film, circularly polarizing plate, and image display device
摘要 A optical film includes a thermoplastic resin and a compound wherein: (1) the absorption spectrum of said compound in solution has at least two absorption maxima in the 200-350 nm wavelength range; (2) letting λmax1 represent the wavelength of a first absorption maximum (one of the aforementioned absorption maxima) and letting λmax2 represent the wavelength of a second absorption maximum (another of the aforementioned absorption maxima) at a shorter wavelength than the first absorption maximum, (λmax1−λmax2) is at least 20 nm; (3) the aspect ratio of the molecules of the compound is at least 1.70; (4) each molecule of the compound has a non-aromatic hydrocarbon ring, a non-aromatic heterocycle, or an aromatic heterocycle; (5) the in-plane-retardation increase sensitivity of the compound is at least 0.1; 110 nm≦R0(550)≦170 nm; 0.72≦R0(450)/R0(550)≦0.96; and 0.83≦R0(550)/R0(650)≦0.97.
申请公布号 US9500790(B2) 申请公布日期 2016.11.22
申请号 US201314379994 申请日期 2013.02.19
申请人 KONICA MINOLTA, INC. 发明人 Fujisawa Rie;Kogure Midori;Suzuki Takatugu
分类号 G02B5/30;G02B27/28;G02B5/22;G02B5/20;G02B5/32;C07D265/22;C07D207/452;C07D277/66;C07D209/86;C07D295/18;C07D213/64;C07D307/60;G02F1/13363;G02B27/26;G02B1/111;H01L51/52;G02F1/1335 主分类号 G02B5/30
代理机构 Holtz, Holtz & Volek PC 代理人 Holtz, Holtz & Volek PC
主权项 1. An optical film comprising a thermoplastic resin and at least one compound which satisfies all of the following requirements (1) to (5): (1) the compound has at least two absorption maxima in a wavelength region of from 200 nm to 350 nm in a solution absorption spectrum; (2) when a wavelength of a first absorption maximum of the two absorption maxima in the wavelength region of from 200 nm to 350 nm is designated as λmax1, and a wavelength of a second absorption maximum of the two absorption maxima at shorter wavelengths than the first absorption maximum is designated as λmax2, wherein λmax1−λmax2 is 20 nm or more; (3) an aspect ratio of a molecule of the compound is 1.70 or more; (4) the compound has a non-aromatic hydrocarbon ring, an aromatic heterocyclic ring, or a non-aromatic heterocyclic ring in the molecule; and (5) for a sample film having a thickness of 60 μm and containing the thermoplastic resin and the compound at a proportion of 1% by mass with respect to the thermoplastic resin, when a retardation in an in-plane direction at a wavelength of 550 nm before stretching of the sample film is designated as R0A0(550), and a retardation in the in-plane direction at a wavelength of 550 nm after stretching at a temperature higher by 25° C. than a glass transition temperature of the sample film is designated as R0A1(550), so that a in-plane retardation sensitivity obtained by dividing R0A1(550)−R0A0(550) by actual stretch ratio of the sample film is designated as A; and for a blank film having a thickness of 60 μm and formed from the thermoplastic resin, when a retardation in the in-plane direction at a wavelength of 550 nm before stretching of the blank film is designated as R0B0(550), and a retardation in the in-plane direction at a wavelength of 550 nm after stretching at a temperature higher by 25° C. than a glass transition temperature of the blank film is designated as R0B1(550), so that an in-plane retardation sensitivity obtained by dividing R0B1(550)−R0B0(550) by actual stretch ratio of the blank film is designated as B, an in-plane retardation increase sensitivity defined by A−B is 0.1 or more, wherein when the retardations in the in-plane direction measured at wavelengths of 450 nm, 550 nm and 650 nm are designated as R0(450), R0(550) and R0(650), respectively, the following Formulas (a) to (c) are all satisfied: 110 nm≦R0(550)≦170 nm;  (a)0.72≦R0(450)/R0(550)≦0.96; and  (b)0.83≦R0(550)/R0(650)≦0.97.  (c)
地址 Tokyo JP
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