发明名称 FORMATION OF CHROMANES BASED ON INTERMOLECULAR REACTION OF ALKYNES WITH DIMETHYLFURAN IN THE PRESENCE OF GOLD(I) COMPLEXES
摘要 The present invention relates to a method of preparing chromanes from 2,5-dimethylfuran and substituted alkynes comprising an long chain unsaturated alkyl group as substituent in the alpha position of a substituted phenol followed by oxidation, reduction and acid ring closure. It is particularly advantageous to use 2,5-dimethylfuran as this offers an ecological beneficial synthesis of β-tocopherol.
申请公布号 WO2016096566(A1) 申请公布日期 2016.06.23
申请号 WO2015EP79111 申请日期 2015.12.09
申请人 DSM IP ASSETS B.V. 发明人 LETINOIS, ULLA;NETSCHER, THOMAS
分类号 C07C37/14;C07C39/16 主分类号 C07C37/14
代理机构 代理人
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