Process for the preparation of membrane electrode assemblies (MEAs)

摘要

PBI-based MEAs for high temperature Polymer Electrolyte Membrane Fuel Cell (PEMFC) were prepared by direct hot pressing of catalyst layer on Teflon sheets on to both sides of phosphoric acid doped PBI membrane (decal transfer). These MEAs show two times higher performance compared to the MEAs prepared by normal brush coating method on GDL at an operating temperature of 160° C.

主权项

1. A process for the preparation of a membrane electrode assembly (MEA) comprising:
a. hot pressing a poly benzimidazole membrane (PBI) doped with phosphoric acid at a temperature of 130° C., at a pressure of about 1.6 tons per square inch for 30 minutes; b. hot pressing the membrane as obtained in step (a) again with electrodes at a temperature of 130° C. at about 1.6 tons per square inch for a period of 15 minutes to obtain an electrolyte membrane; c. directly transferring a catalyst layer comprising Pt/carbon in the range of 0.15-0.3 mg/cm2 from a nonporous support on to the electrolyte membrane as obtained in step (b) during hot pressing to obtain a membrane electrode assembly (MEA).