N-Thio-anthranilamid compounds and their use as pesticides

摘要

N-Thio-anthranilamid compounds of formula (I);
wherein A is A1;
wherein the variables and the indices are as defined per the description, processes for preparing the compounds I, pesticidal compositions comprising compounds I, use of compounds I for the control of insects, acarids or nematodes, and methods for treating, controlling, preventing or protecting animals against infestation or infection by parasites by use of compounds of formula I.

主权项

1. A compound of formula I having the following structure, wherein, R1 is hydrogen; or C1-C10-alkyl, C2-C10-alkenyl, C2-C10-alkynyl, or C3-C8-cycloalkyl, each of which is unsubstituted or substituted with 1 to 5 groups independently selected from halogen, cyano, nitro, hydroxy, C1-C10-alkoxy, C1-C10-alkylthio, C1-C10-alkylsulfinyl, C2-C10-alkoxycarbonyl, C1-C10-alkylamino, di(C1-C10-alkyl)amino and C3-C8-cycloalkylamino; or C1-C10-alkylcarbonyl, C1-C10-alkoxycarbonyl C1-C10-alkylaminocarbonyl, di(C1-C10-alkyl)aminocarbonyl; A is a group selected from A1 wherein, # denotes the binding site, and R2 and R3 each independently are R6, —C(═G)R7, —C(═NOR7)R7, —C(═NNR72)R7, —C(═G)OR7, —C(═G)NR72, —OC(═G)R7, —OC(═G)OR7, —NR7C(═G)R7, —N[C(═G)R7]2, —NR7C(═G)OR7, —C(═G)NR7—NR72, —C(═G)NR7—NR7[C(═G)R7], —NR7—C(═G)NR72, —NR7—NR7C(═G)R7, —NR7—N[C(═G)R7]2, —N[(C═G)R7]—NR72, —NR7—NR7[(C═G)GR7], —NR7[(C═G)NR72, —NR7[C═NR7]R7, —NR7(C═NR7)NR72, —O—NR72, —O—NR7(C═G)R7, —SO2NR72, —NR7SO2R7, —SO2OR7, —OSO2R7, —OR7, —NR72, —SR7, —SiR73, —PR72, —P(═G)R7, —SOR7, —SO2R7, —PG2R72, or —PG3R72; or R2 and R3 together with the sulfur atom to which they are attached form a saturated, partially unsaturated or unsaturated 3- to 8-membered ring which contains 1 to 4 heteroatoms selected from oxygen, nitrogen, sulfur, which ring can be fused with one or two saturated, partially unsaturated or unsaturated 5- to 6-membered rings which may contain 1 to 4 heteroatoms selected from oxygen, nitrogen, sulfur, wherein all of the above rings are unsubstituted or substituted by any combination of 1 to 6 groups R8; G is oxygen or sulfur; R6 is C1-C20-alkyl, C2-C20-alkenyl, C2-C20-alkynyl, C3-C8-cycloalkyl, C3-C8-cycloalkenyl, C3-C8-cycloalkynyl, phenyl, naphthyl, biphenyl, or a saturated, partially unsaturated or unsaturated 3- to 8-membered ring system which contains 1 to 4 heteroatoms selected from oxygen, nitrogen, sulfur, wherein all of these groups are unsubstituted or substituted by any combination of 1 to 6 groups R8; R7 is hydrogen or R6; R8 is R9; or two groups R8 together with the atoms to which they are attached form a saturated, partially unsaturated or unsaturated 3- to 8-membered ring system which may contain 1 to 4 heteroatoms/heterogroups selected from oxygen, nitrogen, sulfur, SO and SO2, and which ring system is unsubstituted or substituted with any combination of 1 to 6 groups R9; R9 is R10, R11, —C(═G)R10, —C(═NOR10)R10, —C(═NNR102)R10, —C(═G)OR10, —C(═G)NR102, —OC(═G)R10, —OC(═G)OR10, —NR10C(═G)R10, —N[C(═G)R10]2, —NR10C(═G)OR10, —C(═G)NR10—NR102, —C(═G)NR10—NR10[C(═G)R10], —NR10—C(═G)NR102, —NR10—NR10C(═G)R10, —NR10—N[C(═G)R10]2, —N[(C═G)R10]—NR102, —NR10—NR10[(C═G)GR10], —NR10[(C═G)NR102, —NR10[C═NR10]R10, —NR10(C═NR10)NR102, —O—NR102, —O—NR10(C═G)R10, —SO2NR102, —NR10SO2R10, —SO2OR10, —OSO2R10, —OR10, —NR102, —SR10, —SiR103, —PR102, —P(═G)R10, —SOR10, —SO2R10, —PG2R102, —PG3R102 or two groups R9 together are (═G), (═N—R10), (═CR102), (═CHR10), or (═CH2); R10 is C1-C10-alkyl, C2-C10-alkenyl, C2-C10-alkynyl, C3-C8-cycloalkyl, C4-C8-cycloalkenyl, C3-C8-cycloalkyl-C1-C4-alkyl, C4-C8-cycloalkenyl-C1-C4-alkyl, C3-C8-cycloalkyl-C2-C4-alkenyl, C4-C8-cycloalkenyl-C2-C4-alkenyl, C1-C10-alkyl-C3-C8-cycloalkyl, C2-C10-alkenyl-C3-C8-cycloalkyl, C2-C10-alkynyl-C3-C8-cycloalkyl, C1-C10-alkyl-C4-C8-cycloalkenyl, C2-C10-alkenyl-C4-C8-cycloalkenyl, C2-C10-alkynyl-C4-C8-cycloalkenyl, a saturated, partially unsaturated or unsaturated 3- to 8-membered ring system which contains 1 to 4 heteroatoms selected from oxygen, nitrogen, sulfur; wherein the above groups are unsubstituted or substituted with any combination of from 1 to 6 groups R11; R11 is halogen, cyano, nitro, hydroxy, mercapto, amino, formyl, C1-C10-alkylcarbonyl, C1-C10-alkoxy, C2-C10-alkenyloxy, C2-C10-alkynyloxy, C1-C10-haloalkoxy, C3-C10-haloalkenyloxy, C3-C10-haloalkynyloxy, C3-C8-cycloalkoxy, C4-C8-cycloalkenyloxy, C3-C8-halocycloalkoxy, C4-C8-halocycloalkenyloxy, C3-C8-cycloalkyl-C1-C4-alkoxy, C4-C8-cycloalkenyl-C1-C4-alkoxy, C3-C8-cycloalkyl-C2-C4-alkenyloxy, C4-C8-cycloalkenyl-C2-C4-alkenyloxy, C1-C10-alkyl-C3-C8-cycloalkoxy, C1-C10-alkenyl-C3-C8-cycloalkoxy, C1-C10-alkynyl-C3-C8-cycloalkoxy, C1-C10-alkyl-C3-C8-cycloalkenyloxy, C1-C10-alkenyl-C3-C8-cycloalkenyloxy, C1-C4-alkoxy-C2-C10-alkenyloxy, mono- or di(C1-C10-alkyl)carbamoyl, mono- or di(C1-C10-haloalkyl)carbamoyl, mono- or di(C3-C8-cycloalkyl)carbamoyl, C1-C10-alkoxycarbonyl, C3-C8-cycloalkoxycarbonyl, C1-C10-alkylcarbonyloxy, C3-C8-cyclo alkylcarbonyloxy, C1-C10-haloalkoxycarbonyl, C1-C10-haloalkylcarbonyloxy, C1-C10-alkanamido, C1-C10-haloalkanamido, C2-C10-alkenamido, C3-C8-cycloalkanamido, C3-C8-cycloalkyl-C1-C4-alkanamido, C2-C10-alkenylthio, C2-C10-alkynylthio, C1-C10-haloalkylthio, C2-C10-haloalkenylthio, C2-C10-haloalkynylthio, C3-C8-cycloalkylthio, C3-C8-cycloalkenylthio, C3-C8-halocycloalkylthio, C3-C8-halocycloalkenylthio, C3-C8-cycloalkyl-C4-C8-cycloalkenyl-C1-C4-alkylthio, C3-C8-cycloalkyl-C2-C4-alkenylthio, C4-C8-cycloalkenyl-C2-C4-alkenylthio, C1-C10-alkyl-C3-C8-cycloalkylthio, C1-C10-alkenyl-C3-C8-cycloalkylthio, C1-C10-alkynyl-C3-C8-cycloalkylthio, C1-C10-alkyl-C3-C8-cycloalkenylthio, C1-C10-alkenyl-C3-C8-cycloalkenylthio, C1-C10-alkylsulfinyl, C2-C10-alkenylsulfinyl, C2-C10-alkynylsulfinyl, C1-C10-haloalkylsulfinyl, C2-C10-haloalkenylsulfinyl, C2-C10-haloalkynylsulfinyl, C3-C8-cycloalkylsulfinyl, C3-C8-cycloalkenylsulfinyl, C3-C8-halocycloalkylsulfinyl, C3-C8-halocycloalkenylsulfinyl, C3-C8-cycloalkyl-C1-C4-alkylsulfinyl, C4-C8-cycloalkenyl-C1-C4-alkylsulfinyl, C3-C8-cycloalkyl-C2-C4-alkenylsulfinyl, C4-C8-cycloalkenyl-C2-C4-alkenylsulfinyl, C1-C10-alkyl-C3-C8-cycloalkylsulfinyl, C1-C10-alkenyl-C3-C8-cycloalkylsulfinyl, C1-C10-alkynyl-C3-C8-cycloalkylsulfinyl, C1-C10-alkyl-C3-C8-cycloalkenylsulfinyl, C1-C10-alkenyl-C3-C8-cycloalkenylsulfinyl, C1-C10-alkylsulfonyl, C2-C10-alkenylsulfonyl, C2-C10-alkynylsulfonyl, C1-C10-haloalkylsulfonyl, C2-C10-haloalkenylsulfonyl, C2-C10-haloalkynylsulfonyl, C3-C8-cycloalkylsulfonyl, C3-C8-cycloalkenylsulfonyl, C3-C8-halocycloalkylsulfonyl, C3-C8-halocycloalkenylsulfonyl, C3-C8-cycloalkyl-C1-C4-alkylsulfonyl, C4-C8-cycloalkenyl-C1-C4-alkylsulfonyl, C3-C8-cycloalkyl-C2-C4-alkenylsulfonyl, C4-C8-cycloalkenyl-C2-C4-alkenylsulfonyl, C1-C10-alkyl-C3-C8-cycloalkylsulfonyl, C1-C10-alkenyl-C3-C8-cycloalkylsulfonyl, C1-C10-alkynyl-C3-C8-cycloalkylsulfonyl, C1-C10-alkyl-C3-C8-cycloalkenylsulfonyl, C1-C10-alkenyl-C3-C8-cycloalkenylsulfonyl, C1-C10-alkylamino, C2-C10-alkenylamino, C2-C10-alkynylamino, C1-C10-alkyl-C2-C10-alkynylamino, C1-C10-haloalkylamino, C2-C10-haloalkenylamino, C2-C10-haloalkynylamino, C3-C8-cycloalkylamino, C3-C8-cycloalkenylamino, C3-C8-halocycloalkylamino, C3-C8-halocycloalkenylamino, C3-C8-cycloalkyl-C1-C4-alkylamino, C4-C8-cycloalkenyl-C1-C4-alkylamino, C3-C8-cycloalkyl-C2-C4-alkenylamino, C4-C8-cycloalkenyl-C2-C4-alkenylamino, C1-C10-alkyl-C3-C8-cycloalkylamino, C1-C10-alkenyl-C3-C8-cycloalkylamino, C1-C10-alkynyl-C3-C8-cycloalkylamino, C1-C10-alkyl-C3-C8-cycloalkenylamino, C1-C10-alkenyl-C3-C8-cycloalkenylamino, tri(C1-C10-alkyl)silyl, aryl, aryloxy, arylthio, arylamino, aryl-C1-C4-alkoxy, aryl-C3-C4-alkenyloxy, aryl-C1-C4-alkylthio, aryl-C2-C4-alkenylthio, aryl-C1-C4-alkylamino, aryl-C3-C4-alkenylamino, triarylsilyl, wherein aryl is phenyl, naphthyl or biphenyl, or a saturated, partially unsaturated or unsaturated 3- to 8-membered ring system which contains 1 to 4 heteroatoms selected from oxygen, nitrogen, sulfur, wherein said aryl and heteroatom cyclic ring systems are unsubstituted or substituted with any combination of from 1 to 6 groups selected from halogen, cyano, nitro, amino, hydroxy, mercapto, C1-C4-alkyl, C1-C4-haloalkyl, C3-C8-cycloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-haloalkylthio, di(C1-C4-alkyl)amino, C1-C4-alkylamino, C1-C4-haloalkylamino, formyl and C1-C4-alkylcarbonyl; Q1 is hydrogen, halogen, cyano, C1-C4-alkyl, or C1-C4-haloalkyl; Q2 is halogen, cyano, C1-C4-alkyl, or C1-C4-haloalkyl; Q3 is halogen, C1-C4-haloalkyl, or C1-C4-haloalkoxy; Q4 is halogen or C1-C4-haloalkyl and is in the ortho position; X and Y are oxygen; W is N; n is 0 or 1; V and V′ each independently are N or CH; and p is 1;or the enantiomers or salts or N-oxides thereof.