发明名称 |
PRODUCTION OF PROPYLENE VIA SIMULTANEOUS DEHYDRATION AND SKELETAL ISOMERISATION OF ISOBUTANOL ON ACID CATALYSTS FOLLOWED BY METATHESIS |
摘要 |
A process for production of propylene can include simultaneously subjecting isobutanol to dehydration and skeletal isomerization to make a mixture of n-butenes and iso-butene. The n-butenes can be subjected to methathesis. The process can include introducing isobutanol into a dehydration/isomerization reactor and contacting the isobutanol with a catalyst at conditions effective to dehydrate and skeletal isomerase the isobutanol to make a mixture of n-butenes and iso-butene. A mixture of n-butenes and iso-butene can be recovered and fractionated to produce an n-butenes stream. The n-butenes stream can be sent to a methathesis reactor and contacted with a catalyst at conditions effective to produce propylene. A stream can be recovered from the methathesis reactor that includes propylene, unreacted n-butenes, heavies, and optionally unreacted ethylene. The stream can be fractionated to recover propylene, and the unreacted n-butenes and unreacted ethylene can optionally be recycled to the methathesis reactor. |
申请公布号 |
EP2547639(B1) |
申请公布日期 |
2016.08.24 |
申请号 |
EP20110708460 |
申请日期 |
2011.03.15 |
申请人 |
TOTAL RESEARCH & TECHNOLOGY FELUY |
发明人 |
VERMEIREN, WALTER;ADAM, CINDY;MINOUX, DELPHINE |
分类号 |
C07C1/24;B01J29/06;B01J29/40;B01J29/85;C07C5/25;C07C5/27;C07C6/04;C07C7/148;C07C7/177;C07C11/00;C07C11/06;C07C11/08;C07C11/09 |
主分类号 |
C07C1/24 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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