| 摘要 |
A method of carrying out a reaction comprising the steps of: mixing at least one organic reaction component with at least one fluorous reaction component having the formula:wherein n is 1 or 2, R is a C1-C6 alkyl group, X<1 >and X<2 >are independently, the same or different, H, F, Cl, Br, I, N3, OR<1>, OOR<1 >SR<1>, SeR<1>, CN, NC, NR<1>R<2>, an aryl group, a heteroaryl group, an alkyl group of 1 to 20 carbons, an alkenyl group, an alkynyl group, -C(O)R<3>, M((Rs')(Rf'))3, OM((Rs')(Rf'))3 or OOM((Rs')Rf'))3, wherein M is Si, Ge, or Sn, and wherein R<1 >and R<2 >are each independently the same or different H, an alkyl group, -SO2R<3 >or -C(O)R<3>, wherein R<3 >is an alkyl group or an aryl group, and wherein Rs and Rs' are each independently the same or different a spacer group, and wherein Rf and Rf' are each independently the same or different a fluorous group; carrying out a reaction to produce an organic product; and after producing the organic product, separating any excess of the fluorous reaction component and any fluorous byproduct of the fluorous reaction component using a fluorous separation technique. Several compounds have the formula: |
