发明名称 |
Process for hydrogenolysis of glycerol |
摘要 |
A process for the hydrogenolysis of glycerol to produce propylene glycol as the major product comprising contacting the glycerol with hydrogen in the presence of a heterogeneous catalyst under conditions for the formation of propylene glycol is disclosed. In particular, propylene glycol is formed with a selectivity of greater than about 90%. |
申请公布号 |
US9464015(B2) |
申请公布日期 |
2016.10.11 |
申请号 |
US201414769112 |
申请日期 |
2014.03.06 |
申请人 |
UNIVERSITY OF SASKATCHEWAN |
发明人 |
Dalai Ajay Kumar;Sharma Rajesh Vishnudev;Kumar Pardeep |
分类号 |
C07C29/60;B01J23/00;B01J23/86;B01J37/03;B01J37/18;B01J38/12;B01J23/94;B01J35/00;B01J35/10 |
主分类号 |
C07C29/60 |
代理机构 |
Bereskin & Parr LLP/S.E.N.C.R.L., s.r.l. |
代理人 |
Bereskin & Parr LLP/S.E.N.C.R.L., s.r.l. ;Folkins Patricia |
主权项 |
1. A process for the hydrogenolysis of glycerol to produce propylene glycol comprising:
(a) contacting the glycerol with hydrogen in the presence of a heterogeneous catalyst under conditions for the formation of propylene glycol; and (b) optionally isolating the propylene glycol, wherein the heterogeneous catalyst comprises Cu, Cr, Zn and Zr. |
地址 |
Saskatoon, Saskatchewan CA |