发明名称 Process for hydrogenolysis of glycerol
摘要 A process for the hydrogenolysis of glycerol to produce propylene glycol as the major product comprising contacting the glycerol with hydrogen in the presence of a heterogeneous catalyst under conditions for the formation of propylene glycol is disclosed. In particular, propylene glycol is formed with a selectivity of greater than about 90%.
申请公布号 US9464015(B2) 申请公布日期 2016.10.11
申请号 US201414769112 申请日期 2014.03.06
申请人 UNIVERSITY OF SASKATCHEWAN 发明人 Dalai Ajay Kumar;Sharma Rajesh Vishnudev;Kumar Pardeep
分类号 C07C29/60;B01J23/00;B01J23/86;B01J37/03;B01J37/18;B01J38/12;B01J23/94;B01J35/00;B01J35/10 主分类号 C07C29/60
代理机构 Bereskin & Parr LLP/S.E.N.C.R.L., s.r.l. 代理人 Bereskin & Parr LLP/S.E.N.C.R.L., s.r.l. ;Folkins Patricia
主权项 1. A process for the hydrogenolysis of glycerol to produce propylene glycol comprising: (a) contacting the glycerol with hydrogen in the presence of a heterogeneous catalyst under conditions for the formation of propylene glycol; and (b) optionally isolating the propylene glycol, wherein the heterogeneous catalyst comprises Cu, Cr, Zn and Zr.
地址 Saskatoon, Saskatchewan CA