发明名称 |
RECOVERY OF MOLYBDENUM FROM MOLYBDENUM BEARING SULFIDE MATERIALS BY BIOLEACHING IN THE PRESENCE OF IRON |
摘要 |
<p>The invention relates to a method of recovering molybdenum from a molybdenum bearing sulfide material. The material is contacted with a leaching solution in the presence of iron compounds and mesophilic or thermophilic iron oxidizing microorganisms and subsequently, a leaching process is performed by controlling the molar ratio of dissolved ferric iron to dissolved molybdenum. Preferably, a high amount and molar excess of dissolved iron is used. The presence of high concentrations of ferric iron in bioleach solutions allows iron-oxidizing microorganisms to grow and oxidize iron and bioleach molybdenite at dissolved Mo concentrations as high as 4.4 g/L. Organic metabolites were not required for protecting cells from Mo toxicity. Maximum dissolution rates depend on reactor configuration, with agglomerated material simulating heap leaching of almost 1% Mo/day, but up to 10.2% Mo/day in suspension/stirred reactor configurations, with rate highly dependent on temperature within the range of 25°C to 40°C. The ultimate extent of Mo removal from the molybdenum bearing sulfide material is 89%. Finally, molybdenum is recovered from a leach residue of the leaching process.</p> |
申请公布号 |
WO2008015108(A1) |
申请公布日期 |
2008.02.07 |
申请号 |
WO2007EP57455 |
申请日期 |
2007.07.19 |
申请人 |
H.C. STARCK GMBH;KUMMER, WOLFGANG;GUTKNECHT, WILFRIED;OLSON, GERGORY JAMES;CLARK, THOMAS, R. |
发明人 |
KUMMER, WOLFGANG;GUTKNECHT, WILFRIED;OLSON, GERGORY JAMES;CLARK, THOMAS, R. |
分类号 |
C22B3/18;C22B3/08;C22B34/34 |
主分类号 |
C22B3/18 |
代理机构 |
|
代理人 |
|
主权项 |
|
地址 |
|