发明名称 |
IN SITU PREPARATION OF A BIMORPHOLOGICAL LATEX |
摘要 |
The present invention relates to an in situ method for preparing a bimorphological aqueous dispersion of first polymer particles with protuberating phosphorus acid cores and second polymer particles without protuberating cores. The method provides a more efficient way of making compositions for pigmented coating formulations. |
申请公布号 |
US2016280903(A1) |
申请公布日期 |
2016.09.29 |
申请号 |
US201615075241 |
申请日期 |
2016.03.21 |
申请人 |
Rohm and Haas Company |
发明人 |
Bohling James C.;Brownell Arnold S.;Gao Wei;Tiwary Yogesh |
分类号 |
C08L33/12;C08L33/08 |
主分类号 |
C08L33/12 |
代理机构 |
|
代理人 |
|
主权项 |
1. An in situ method for preparing a bimorphological aqueous dispersion of polymer particles comprising the steps of:
a) mixing together an aqueous dispersion of phosphorus acid-functionalized acrylic-based first seed polymer particles having a volume average particle size in the range of from 40 nm to 85 nm with an aqueous dispersion of acrylic-based second seed polymer particles comprising a substantial absence of phosphorus acid functionality and having a volume average particle size in the range of from 20 nm to 80 nm; b) contacting monomers with the aqueous dispersions of the first and second seed polymer particles under emulsion polymerization conditions to form a dispersion of 1) polymer particles with a protuberating phosphorus acid functionalized core; and 2) polymer particles without a protuberating core; and wherein the weight-to-weight ratio of particles with the protuberating phosphorus acid functionalized core to particles without a protuberating core is in the range of 25:75 to 75:25. |
地址 |
Philadelphia PA US |