发明名称 |
PREPARATION OF TITANIUM CATECHOLATE COMPLEXES IN AQUEOUS SOLUTION USING TITANIUM TETRACHLORIDE OR TITANIUM OXYCHOLORIDE |
摘要 |
Titanium coordination complexes, particularly titanium catecholate complexes, can be attractive active materials for use in flow batteries. However, such coordination complexes can be difficult to prepare from inexpensive starting materials, particularly in aqueous solutions. Titanium oxychloride and titanium tetrachloride represent relatively inexpensive titanium sources that can be used for preparing such coordination complexes. Methods for preparing titanium catecholate complexes can include combining one or more catecholate ligands and titanium oxychloride in an aqueous solution, and reacting the one or more catecholate ligands with the titanium oxychloride in the aqueous solution to form the titanium catecholate complex. Titanium tetrachloride can be used as a precursor for forming the titanium oxychloride in situ. In some instances, the titanium catecholate complex can be isolated in a solid form, which can be substantially free of alkali metal ions. |
申请公布号 |
WO2016149336(A1) |
申请公布日期 |
2016.09.22 |
申请号 |
WO2016US22597 |
申请日期 |
2016.03.16 |
申请人 |
LOCKHEED MARTIN ADVANCED ENERGY STORAGE, LLC |
发明人 |
KING, Evan, R.;PICKETT, Brian, D.;GOODMAN, Malcolm;FU, Guoyi |
分类号 |
H01M4/36;C07F7/28 |
主分类号 |
H01M4/36 |
代理机构 |
|
代理人 |
|
主权项 |
|
地址 |
|