发明名称 HEAT-EXPANDABLE MICROSPHERES, PROCESS FOR PRODUCING THE SAME, AND APPLICATION THEREOF
摘要 Heat-expandable microspheres composed of a thermoplastic resin shell and a thermally-vaporizable blowing agent encapsulated therein, and having an average particle size ranging from 1 to 100 μm. The amount of DMF-insoluble matter (G1) and the amount of DMF-MEK-insoluble matter (G2) constituting the heat-expandable microspheres satisfy 1.05<G2/G1. The expansion of the heat-expandable microspheres satisfy Hmax/Tmax≧13 (μm/° C.) where Hmax and Tmax are as defined herein. Also disclosed in a process for producing the heat-expandable microspheres which includes preparing an aqueous suspension comprising oily globules dispersed in an aqueous dispersion medium containing a hydrophilic cross-linking agent, wherein the oily globules are made of an oily mixture comprising the blowing agent and a monomer component; and polymerizing the monomer component.
申请公布号 US2016237234(A1) 申请公布日期 2016.08.18
申请号 US201415028133 申请日期 2014.10.02
申请人 MATSUMOTO YUSHI-SEIYAKU CO., LTD. 发明人 TAYAGAKI Naoya;MIKI Katsushi
分类号 C08J9/20;C08J9/228 主分类号 C08J9/20
代理机构 代理人
主权项 1. Heat-expandable microspheres comprising a thermoplastic resin shell and a thermally-vaporizable blowing agent encapsulated therein, and having an average particle size ranging from 1 to 100 μm; wherein an amount of DMF-insoluble matter (G1) and an amount of DMF-MEK-insoluble matter (G2) constituting the heat-expandable microspheres satisfy the expression 1.05<G2/G1.
地址 Yao-shi, Osaka JP