发明名称 CATALYSTS COMPRISING CYCLIC ACYLUREA COMPOUNDS AND OXIDATION AND NITRATION REACTIONS OF ORGANIC COMPOUNDS IN THE PRESENCE OF THE SAME
摘要 A catalyst of the invention includes a cyclic acylurea compound having a cyclic acylurea skeleton represented by following Formula (I): <CHEM> wherein R is a hydrogen atom or a hydroxyl-protecting group; n is 1 or 2; G is a carbon atom or a nitrogen atom, where two Gs are the same or different when n is 2. The catalyst may include the cyclic acylurea compound and a metallic compound in combination. In the presence of the catalyst, (A) a compound capable of forming a radical is allowed to react with (B) a radical scavenging compound and thereby yields an addition or substitution reaction product of the compound (A) and the compound (B) or a derivative thereof. This catalyst can produce an organic compound with a high selectivity in a high yield as a result of, for example, an addition or substitution reaction under mild conditions.
申请公布号 EP1459804(A1) 申请公布日期 2004.09.22
申请号 EP20020791966 申请日期 2002.12.05
申请人 DAICEL CHEMICAL INDUSTRIES, LTD. 发明人 ISHII, YASUTAKA;HIRAI, NARUHISA
分类号 B01J31/02;B01J31/26;C07C29/50;C07C45/36;C07C49/453;C07C49/675;C07C51/265;C07C51/31;C07C67/29;C07C205/05;C07C205/44;C07C205/57;C07C253/30;C07C255/57;C07D251/34 主分类号 B01J31/02
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