发明名称 Molybdenum trioxide catalyzed fluorination reactions
摘要 Disclosed is a method of fluorinating a substrate having the general formula where each R is independently selected from halogen, alkyl from C1 to C12, aryl from C6 to C12, alkoxide from C1 to C12, aryloxide from C6 to C12, nitro, amino, alkylamino from C1 to C12, and arylamino from C6 to C12, each X is independently selected from halogen and at least one X is chlorine or bromine, each m is independently selected from 0 to 5, n is 0 or 1, p is 0 or 1, q is 0 or 1, and n+p+q is 1. The substrate is heated to a temperature of about 40 to about 100 DEG C. and is reacted with a fluorinating agent in the presence of about 0.05 to about 2 wt % molybdenum trioxide. The composition of the substrate, the catalyst, and the fluorinating agent is also disclosed.
申请公布号 US6166272(A) 申请公布日期 2000.12.26
申请号 US19990373133 申请日期 1999.08.12
申请人 OCCIDENTAL CHEMICAL CORPORATION 发明人 MANDAL, SANJAY
分类号 C07B39/00;C07C17/20;C07C205/11;(IPC1-7):C07C22/00;C07C41/00;C07C209/00 主分类号 C07B39/00
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